Suzuki−Miyaura Cross-Coupling of Potassium Trifluoroboratohomoenolates
| Autor: | Daniel E. Petrillo, Gary A. Molander |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Boron Compounds
Bromides chemistry.chemical_classification Ketone Aryl Potassium Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Coupling (electronics) chemistry.chemical_compound Chlorides chemistry Borates Electrophile Organic chemistry Organic Chemicals Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 10:1795-1798 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol800357c |
| Popis: | Ketone-, ester-, and amide-containing potassium trifluoroboratohomoenolates were prepared in good to excellent yields from the corresponding unsaturated carbonyl compounds. They were shown to be effective coupling partners in the Suzuki-Miyaura reaction with a variety of electrophiles including electron-rich and electron-poor aryl bromides and -chlorides. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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