6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)
| Autor: | Carlos Cativiela, Meghan G. Finn, David Díaz Díaz, Lennart Niehues, Thimo Huber |
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| Přispěvatelé: | Consejo Superior de Investigaciones Científicas (España), Ministerio de Ciencia e Innovación (España), Gobierno de Aragón, European Commission, University of Regensburg |
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: |
Nucleophilic addition
Trimethylsilyl Chiral 1 2-diamines Organic Chemistry ComputingMilieux_LEGALASPECTSOFCOMPUTING Biochemistry Medicinal chemistry Benzaldehyde chemistry.chemical_compound salen ligands chiral 1 2-diamines alkynes nucleophilic addition chemistry Alkynes Salen ligands Organic chemistry Phenol 570 Biowissenschaften Biologie ddc:570 Physical and Theoretical Chemistry Derivative (chemistry) |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| Popis: | This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license. Functionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,2-diphenylethane-1,2-diamine (2) and 3-tert-butyl-2-hydroxy-5-((trimethylsilyl)ethynyl) benzaldehyde (1) under refluxing conditions. The title compound was characterized by 1H-NMR, 13C-NMR, FT-IR, high-resolution mass spectrometry, optical rotation and melting point determination. We thank CSIC (project PIE 200980I059) and University of Regensburg (Anschubfinanzierung von Wissenschaftlichen Projekten-2011), Ministerio de Ciencia e Innovación – FEDER (CTQ2010-17436) and Gobierno de Aragón-FSE (research group E40) for financial support. |
| Databáze: | OpenAIRE |
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