General Way To Construct Micro- and Mesoporous Metal–Organic Framework-Based Porous Liquids

Autor:	Biao Yuan, Lihan Chen, Fang Wang, Tao Li, Yong Jin Lee, Sanfeng He, Yi Yu, Jing Cui, Hongliang Wang
Rok vydání:	2019
Předmět:	Chemical substance Chemistry General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Colloid and Surface Chemistry Chemical engineering Metal-organic framework Porosity Science technology and society Mesoporous material
Zdroj:	Journal of the American Chemical Society. 141:19708-19714
ISSN:	1520-5126 0002-7863
Popis:	We report a new class of porous liquids (PLs) using internally functionalized metal-organic framework (MOF) particles as pore carriers and poly(dimethylsiloxane) as bulky solvents. Using a generalizable noncovalent surface-initiated controlled radical polymerization technique, a series of isoreticular UiO-66 particles were dispersed in a liquid PDMS matrix with excellent homogeneity and colloidal stability. Benefiting from the inherent properties of PDMS, the PLs exhibit low vapor pressure, high thermal stability, and fluidity down to -35 °C. Attributed to the bulkiness of PDMS and its inherent high permeability, the sorption properties of the MOF fillers can be largely retained in their respective PLs as confirmed by low-pressure CO
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60d3dd0404fd27623bedb3ef5957db0a https://doi.org/10.1021/jacs.9b08458 Zobrazit plný text záznamu