The Photo-Favorskii Reaction of p-Hydroxyphenacyl Compounds Is Initiated by Water-Assisted, Adiabatic Extrusion of a Triplet Biradical
| Autor: | Jong I. Lee, Julio F. Mata-Segreda, Jakob Wirz, II Peter G. Conrad, Elizabeth D. Cope, Bruno Hellrung, Richard S. Givens, Marek Mac, Yavor Kamdzhilov, Richard L. Schowen, Dominik Heger |
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| Rok vydání: | 2008 |
| Předmět: |
Reaction mechanism
Aqueous solution Free Radicals Molecular Structure Photochemistry Ultraviolet Rays Water General Chemistry Biochemistry Article Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Quantum Theory Flash photolysis Favorskii reaction Triplet state Protecting group Acetonitrile Benzyl Alcohols Derivative (chemistry) Phenylacetates |
| Zdroj: | Journal of the American Chemical Society. 130:3307-3309 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | The p-hydroxyphenacyl group 1 is an effective photoremovable protecting group, because it undergoes an unusual photo-Favorskii rearrangement concomitant with the fast release ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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