Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand
| Autor: | Takeharu Haino, Ryo Sekiya, Daisuke Shimoyama |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Materials science Metals and Alloys Supramolecular chemistry Sonogashira coupling General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Supramolecular polymers Iodination reaction Suzuki reaction chemistry Polymerization Yield (chemistry) Polymer chemistry Materials Chemistry Ceramics and Composites Surface modification |
| Zdroj: | Chemical Communications. 56(26):3733-3736 |
| Popis: | An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state. This work was supported by the Grants-in-Aid for Scientific Research, JSPS KAKENHI Grant JP15H03817, and by the Grants-in-Aid for Scientific Research on Innovative Areas, JSPS KAKENHI Grants JP19H04585 (Coordination Asymmetry). Funding from The Ogasawara Foundation for the Promotion of Science & Engineering, The Futaba Electronics Memorial Foundation, Nippon Sheet Glass Foundation, Iketani Science and Technology Foundation, Takahashi Industrial and Economic Research Foundation, and Fukuoka Naohiko Memorial Foundation is gratefully acknowledged. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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