Pyrene-Functionalised, Alternating Copolyimide for Sensing Nitroaromatic Compounds

Autor:	Mathew Wade, Howard M. Colquhoun, Stefano Burattini, Wayne Hayes, Barnaby W. Greenland
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Nitro compound Chemical modification Fluorescence Fluorescence spectroscopy chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Copolymer Nitro Pyrene Thin film
Zdroj:	Macromolecular Rapid Communications. 30:459-463
ISSN:	1521-3927 1022-1336
DOI:	10.1002/marc.200800630
Popis:	A novel, pyrene-functionalised copolymer has been synthesised in a single step via imidisation of poly(maleic anhydride-alt-1-octadecene) with 1-pyrenemethylamine, and its potential for the detection of volatile nitro aromatic compounds (NACs) evaluated. The new copolymer forms complexes in solution with NACs such as 2,5-dinitrobenzonitrile, as shown by (1) H NMR, UV-vis and fluorescence spectroscopy. Moreover, thin films of this copolymer, cast from THF solution, undergo almost instantaneous fluorescence quenching when exposed to the vapour of 2,5-dinitrobenzonitrile (a model for TNT) at ambient temperatures and pressures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::607b00cf7a514802691c4d469c957327 https://doi.org/10.1002/marc.200800630 Zobrazit plný text záznamu Plný text