Regioselective Electrophilic C-H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent
| Autor: | Helge Müller-Bunz, Ralte Lalrempuia, Martin Albrecht, Kate F. Donnelly |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Denticity
Stereochemistry Substituent Asterisk-ir Ligands Iridium 010402 general chemistry Ring (chemistry) 01 natural sciences Transition-metals Catalysis Inorganic Chemistry Metal Transmetalation chemistry.chemical_compound Phenyl group Physical and Theoretical Chemistry Pincer complexes 010405 organic chemistry Organic Chemistry Oxidative addition Heterocyclic carbene complexes Regioselectivity Cyclometalation 3. Good health 0104 chemical sciences chemistry visual_art Electrophile visual_art.visual_art_medium Mechanism |
| Zdroj: | Organometallics |
| ISSN: | 0276-7333 |
| DOI: | 10.1021/om300983m |
| Popis: | Transmetalation of a 1,4-diphenyl-substituted 1,2,3-triazolylidene silver complex with an electrophilic metal center, e.g., RuII, IrIII, or RhIII, induces spontaneous and chemoselective cyclometalation involving C–H bond activation of the N-bound phenyl group exclusively. Less electrophilic metals such as IrI, RhI, and PtII yield a monodentate triazolylidene complex, while cyclometalation with borderline cases (PdII) or the activation of the C-bound phenyl ring requires acetate as a promoter. European Research Council Irish Research Council Science Foundation Ireland |
| Databáze: | OpenAIRE |
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