Studies on the Synthesis of Polyarylates with Allylic Side Groups. Part 1. Polyarylates from 2,2-bis (3-allyl-4-hydroxyphenyl)propane and Isophthaloyl Chloride

Autor: Z.K. Brzozowski, I. Zadrozna, E. Lato
Rok vydání: 1994
Předmět:
Zdroj: Polymers and Polymer Composites. 2:147823919400200
ISSN: 1478-2391
0967-3911
DOI: 10.1177/147823919400200406
Popis: Conditions of synthesis of diallyl derivatives of bisphenol-A via a Claisen rearrangement reaction and the preparation of polyarylates from these derivatives via interfacial polycondensation with isophthaloyl chloride were established. The structure of polymers was confirmed by the methods of 1H-NMR, IR, and UV/Vis spectroscopy and elementary analysis. The results of intrinsic viscosity determinations and thermal analysis revealed the high molecular weight and considerable thermal resistance of these polyarylates.
Databáze: OpenAIRE