Experimental and thermodynamic description of ternary Bi-Cu-Ga system

Autor: Duško Minić, Aleksandar Djordjevic, Nadežda Talijan, Yong Du, Milena Premović, Dušan Milisavljević, Milica Tomovic, Aleksandar Markovic, Dragan Manasijević
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Zdroj: Journal of Mining and Metallurgy B: Metallurgy (2017) 53(3):189-201
Journal of Mining and Metallurgy. Section B: Metallurgy, Vol 53, Iss 3, Pp 189-201 (2017)
Journal of Mining and Metallurgy. Section B: Metallurgy
ISSN: 1450-5339
Popis: Phase diagram of the Bi-Cu-Ga ternary system has been investigated experimentally with 27 alloys and analytically by using a Calphad method. Thirteen annealed alloys at 200°C were investigated by using scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Temperatures of phase transformation were determined with 14 alloys which are lying along three vertical sections Bi-Cu0.5Ga0.5, Cu-Bi0.5Ga0.5 and Ga-Bi0.5Cu0.5 by using differential thermal analysis (DTA). Based on the experimental result and by using Calphad method, ternary phase diagrams were constructed with a new description of liquidus phase. Calculated phase diagram and experimentally obtained results are in good agreement. Liquidus projection and invariant reaction were calculated by using new thermodynamic parameters for liquidus phase. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. OI172037]
Databáze: OpenAIRE