Ferroelectricity in the 1 $��$C cm$^{-2}$ range induced by canted antiferromagnetism in (LaMn$_{3}$)Mn$_{4}$O$_{12}$
| Autor: | Andrea Gauzzi, Marine Verseils, F. P. Milton, D. von Dreifus, Ducinei Garcia, P. Bordet, V. Pascotto Gastaldo, A. J. A. de Oliveira, Yannick Klein, Edmondo Gilioli, A. J. Gualdi |
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| Přispěvatelé: | Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Universidade Federal de São Carlos [São Carlos] (UFSCar), Matériaux, Rayonnements, Structure (NEEL - MRS), Institut Néel (NEEL), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Istituto dei Materiali per l'Elettronica ed il Magnetismo [Genova] (IMEM-CNR), National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR), Matériaux, Rayonnements, Structure (MRS), Consiglio Nazionale delle Ricerche (CNR) |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Ferroelectricity Physics and Astronomy (miscellaneous) Multiferroics FOS: Physical sciences 02 engineering and technology 01 natural sciences Thermodynamic properties 0103 physical sciences Antiferromagnetism Perovskites [PHYS]Physics [physics] 010302 applied physics Condensed Matter - Materials Science Condensed matter physics Magnetism Materials Science (cond-mat.mtrl-sci) 021001 nanoscience & nanotechnology Polarization (waves) X-ray diffraction 3. Good health Pyroelectricity Polarization density Lanthanum compounds Perovskite Polarization Single crystals Specific heat Thermal variables measurement Crystallite 0210 nano-technology Monoclinic crystal system |
| Zdroj: | Applied Physics Letters Applied Physics Letters, 2019, 115 (15), pp.152902. ⟨10.1063/1.5108640⟩ Applied Physics Letters, American Institute of Physics, 2019, 115 (15), pp.152902. ⟨10.1063/1.5108640⟩ Applied physics letters (Online) (2019): 152902-1. doi:10.1063/1.5108640 info:cnr-pdr/source/autori:A. Gauzzi; F. Milton; V. Pascotto Gastaldo; M. Verseils; A. Gualdi; D. von Dreifus; Y. Klein; D. Garcia; A.J.A de Oliveira; P. Bordet; E. Gilioli/titolo:Ferroelectricity in the 1 uC cm-2 range induced by canted antiferromagnetism in (LaMn3)Mn4O12/doi:10.1063%2F1.5108640/rivista:Applied physics letters (Online)/anno:2019/pagina_da:152902-1/pagina_a:/intervallo_pagine:152902-1/volume |
| ISSN: | 0003-6951 |
| DOI: | 10.48550/arxiv.1811.07182 |
| Popis: | Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site Mn$^{3+}$ ions at $T_{N,B}$=78 K with record values of remnant electric polarization up to $P$=0.56 $\mu$C cm$^{-2}$. X-ray diffraction measurements indicates an anomalous behavior of the monoclinic $\beta$ angle at $T_{N,B}$, which suggests that $P$ lies in the $ac$-plane, where the moments are collinear, so we conclude that exchange striction is the mechanism of spin-driven ferroelectricity. Polarization values $\sim$3 $\mu$C cm$^{-2}$ are expected in single crystals, which would open the avenue towards practical multiferroic applications. Comment: 5 pages, 5 figures |
| Databáze: | OpenAIRE |
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