The Combination of Charge and Energy Transfer Processes in MOFs for Efficient Photocatalytic Oxidative Coupling of Amines
| Autor: | Yan-Xi Tan, Feng-Juan Zhao, Zhan-Feng Ju, Guoliang Zhang, Daqiang Yuan |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Ligand Electron 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Paddle wheel Benzylamine chemistry Yield (chemistry) Photocatalysis Oxidative coupling of methane Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 59:3297-3303 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Combining electron and energy transfer processes is very significant for efficient photocatalytic oxidation of organic molecules. The first synthesized MOF, Co2(L)(2,6-NDC)2·xguest (FJI-Y10, L = bis(N-pyridyl) tetrachloroperylene peryleneimide, 2,6-NDC = 2,6-naphthalenedicarboxylic acid, FJI = Fujian Institute), shows a 2-fold interpenetrated pcu net, in which the 2,6-NDC ligand connects typical Co2(COO)4 paddle wheel clusters to form square lattices pillared by new PDI-type ligand L. FJI-Y10 as a heterogeneous and recyclable photocatalyst is applied for photo-oxidation of benzylamine and its derivatives with an excellent yield of 100%, which is much higher than that (59%) of the equivalent L ligand as a homogeneous photocatalyst under the same reaction conditions. Such a high-efficiency photocatalytic activity attributes to the combination of charge and energy transfer processes in catalyst FJI-Y10 during the catalytic process. |
| Databáze: | OpenAIRE |
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