Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn(ii ) coordination polymer
| Autor: | E. N. Zorina-Tikhonova, Alexander D. Volodin, Anna V. Vologzhanina, Igor L. Eremenko, Aleksei A. Sidorov, Aleksandr S Chistyakov, Alexander A. Korlyukov |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Ethylene 010405 organic chemistry Coordination polymer Metals and Alloys Solid-state General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Topology (chemistry) |
| Zdroj: | Chemical Communications. 54:13861-13864 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | 1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal-organic framework (MOF) [Zn2(H2O)2(Amal)2(bpe)] to produce a 3D MOF with a new topology. |
| Databáze: | OpenAIRE |
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