Competition between Cation–Solvent and Cation–Anion Interactions in Imidazolium Ionic Liquids with Polar Aprotic Solvents
| Autor: | Marc Bria, Abdenacer Idrissi, Toshiyuki Takamuku, Bogdan A. Marekha, Oleg N. Kalugin, Slobodan Gadžurić |
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| Přispěvatelé: | Department of Inorganic Chemistry, V.N. Karazin Kharkiv National University (KhNU), Centre Commun de Mesures RMN (CCM-RMN), Université de Lille, Sciences et Technologies, Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University [Japon], Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad, Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516 (LASIRE), Centre National de la Recherche Scientifique (CNRS)-Centrale Lille Institut (CLIL)-Institut de Chimie du CNRS (INC)-Université de Lille, Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Centrale Lille Institut (CLIL), Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Intermolecular force
Solvation 02 engineering and technology chemical shift 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Ion ionic liquids [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Solvent nuclear magnetic resonance chemistry.chemical_compound chemistry Amide Ionic liquid Propylene carbonate Polymer chemistry aprotic solvents solvation Physical and Theoretical Chemistry 0210 nano-technology Trifluoromethanesulfonate |
| Zdroj: | ChemPhysChem ChemPhysChem, Wiley-VCH Verlag, 2017, 18 (7), pp.718-721. ⟨10.1002/cphc.201601445⟩ ChemPhysChem, 2017, 18 (7), pp.718-721. ⟨10.1002/cphc.201601445⟩ |
| ISSN: | 1439-4235 1439-7641 |
| Popis: | International audience; The subtle interplay between ion solvation and association was analyzed in mixtures of imidazolium-based ionic liquids (ILs) with polar aprotic solvents. A site-specific pattern of cation–solvent and cation–anion interactions was disclosed by a careful analysis of the 1H and 13C NMR chemical shift dependence of the mixture composition. It was established that the less polar but more donating γ-butyrolactone is more prone to establish H-bonds with the imidazolium-ring hydrogen atoms of the IL cations than propylene carbonate, particularly at the H2 site and at high dilutions xIL |
| Databáze: | OpenAIRE |
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