Origin of embrittlement in metallic glasses
Autor: | William L. Johnson, Marios D. Demetriou, Glenn Garrett, Maximilien Launey |
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Jazyk: | angličtina |
Rok vydání: | 2016 |
Předmět: |
Toughness
Multidisciplinary Materials science Amorphous metal Metallurgy 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Condensed Matter::Disordered Systems and Neural Networks Annealing (glass) Shear modulus Condensed Matter::Soft Condensed Matter Fragility Fracture toughness 0103 physical sciences Physical Sciences Composite material 010306 general physics 0210 nano-technology Glass transition Embrittlement |
Popis: | Owing to their glassy nature, metallic glasses demonstrate a toughness that is extremely sensitive to the frozen-in configurational state. This sensitivity gives rise to “annealing embrittlement,” which is often severe and in many respects limits the technological advancement of these materials. Here, equilibrium configurations (i.e., “inherent states”) of a metallic glass are established around the glass transition, and the configurational properties along with the plane-strain fracture toughness are evaluated to associate the intrinsic glass toughness with the inherent state properties and identify the fundamental origin of embrittlement. The established correlations reveal a one-to-one correspondence between toughness and shear modulus continuous over a broad range of inherent states, suggesting that annealing embrittlement is controlled almost solely by an increasing resistance to shear flow. This annealing embrittlement sensitivity is shown to vary substantially between metallic glass compositions, and appears to correlate well with the fragility of the metallic glass. |
Databáze: | OpenAIRE |
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