Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2 with Epoxides

Autor:	David Hermann Lamparelli, Vito Capaccio, Veronica Paradiso, Carmine Capacchione
Rok vydání:	2020
Předmět:	chemistry.chemical_element Homogeneous catalysis cyclic carbonates lcsh:Chemical technology 010402 general chemistry 01 natural sciences Catalysis lcsh:Chemistry Metal epoxides lcsh:TP1-1185 Physical and Theoretical Chemistry 010405 organic chemistry Ligand carbon dioxide Sulfur containing homogeneous catalysis Sulfur Combinatorial chemistry 0104 chemical sciences lcsh:QD1-999 chemistry Carbon dioxide Cyclic carbonates Epoxides Polycarbonates polycarbonates Homogeneous sulfur visual_art visual_art.visual_art_medium
Zdroj:	Catalysts, Vol 10, Iss 825, p 825 (2020)
ISSN:	2073-4344
DOI:	10.3390/catal10080825
Popis:	Coupling of CO2 with epoxides is a green emerging alternative for the synthesis of cyclic organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to provide a comprehensive overview of metal complexes having sulfur-containing ligands as homogeneous catalytic systems able to efficiently promote this transformation with a concise discussion of the most significant results. The crucial role of sulfur as the hemilabile ligand and its influence on the catalytic activity are highlighted as well.
Databáze:	OpenAIRE
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