Dinuclear [OSSO]-Fe complexes for the reaction of CO2with epoxides

Autor:	Sara D'Aniello, Bernhard Rieger, Veronica Paradiso, Carmine Capacchione, Francesco Della Monica, David Hermann Lamparelli
Jazyk:	angličtina
Rok vydání:	2021
Předmět:	Reaction mechanism chemistry.chemical_compound 010405 organic chemistry Ligand Chemistry Polymer chemistry Propylene carbonate 010402 general chemistry 01 natural sciences Bimetallic strip Catalysis 0104 chemical sciences
Popis:	A dinuclear iron-based catalytic system, bearing a new alkyl-bridged bis-[OSSO]-type ligand, for the coupling of CO2 with epoxides is reported. A turnover frequency up to 1680 h−1 was recorded for propylene carbonate formation. A bimetallic cooperative reaction mechanism is proposed on the basis of kinetic analyses. These results give insights into the development of more efficient catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5e7c7537837f8279cd73405b614b102a http://hdl.handle.net/11386/4770961 Zobrazit plný text záznamu