Water disinfection through photoactive modified titania

Autor: Ajoy Pal, Rohit Kumar, Tapan Dash, Sony Pandey, R. Sakthivel, Diptipriya Sethi, Trupti Das
Rok vydání: 2014
Předmět:
Zdroj: Journal of Photochemistry and Photobiology B: Biology. 130:310-317
ISSN: 1011-1344
DOI: 10.1016/j.jphotobiol.2013.12.003
Popis: TiO(2), N-TiO(2) and S-TiO(2) samples have been prepared by various chemical methods. These samples were characterized by X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), Laser Raman spectrometer, UV-Visible spectrophotometer, field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM). X-ray powder diffraction study reveals that all three samples are single anatase phase of titania and the crystallinity of titania decreases with sulphur doping whereas nitrogen doping does not affect it. UV-Visible (diffuse) reflectance spectra shows that doping of titania with nitrogen and sulphur shift the absorption edge of titania from ultraviolet to visible region. XPS study confirms that both nitrogen and sulphur are well doped in the titania lattice. It is observed that nitrogen occupies at both substitutional and interstitial position in the lattice of titania. FE-SEM and TEM studies demonstrate that the particles are below 50nm range. It is found that S and N doping of titania increased its water disinfection property in the order TiO(2)S-TiO(2)N-TiO(2) under 8W UV/UV-Visible light irradiation.
Databáze: OpenAIRE