Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis

Autor:	Todd B. Marder, Udo Radius, Stephen A. Westcott, Yudha P. Budiman
Rok vydání:	2021
Předmět:	chemistry.chemical_compound chemistry Aryl ddc:540 Fluorine chemistry.chemical_element Organic chemistry Homogeneous catalysis Organic synthesis General Chemistry
Zdroj:	Advanced Synthesis & Catalysis. 363:2224-2255
ISSN:	1615-4169 1615-4150
Popis:	Organoboron compounds are well known building blocks for many organic reactions. However, under basic conditions, polyfluorinated aryl boronic acid derivatives suffer from instability issues that are accelerated in compounds containing an ortho‐fluorine group, which result in the formation of the corresponding protodeboronation products. Therefore, a considerable amount of research has focused on novel methodologies to synthesize these valuable compounds while avoiding the protodeboronation issue. This review summarizes the latest developments in the synthesis of fluorinated aryl boronic acid derivatives and their applications in cross‐coupling reactions and other transformations. image
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5e6000811edaecf868239bf32fe2cfbe https://doi.org/10.1002/adsc.202001291 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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