Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes of N’-(3,5-Dichloro-2-hydroxybenzylidene)-4- fluorobenzohydrazide: Synthesis, Characterization, Crystal Structures and Catalytic Property
| Autor: | Xiao-Ling Zou, H. Y. Liu, Luo-Ju Yang, Ya-Fang Ye, Yi-Shu Yin |
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| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
crystal structure molybdenum complex catalytic property Chemistry Hydrazone Nuclear magnetic resonance spectroscopy Crystal structure Medicinal chemistry vanadium complex Catalysis lcsh:Chemistry Metal hydrazone lcsh:QD1-999 Octahedron Catalytic oxidation visual_art visual_art.visual_art_medium General Earth and Planetary Sciences Single crystal General Environmental Science |
| Zdroj: | Acta Chimica Slovenica, Vol 67, Iss 1, Pp 130-136 (2020) |
| ISSN: | 1580-3155 |
| DOI: | 10.17344/acsi.2019.5286 |
| Popis: | N' -(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H 2 L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] ( 1 ) and dioxidomolybdenum(VI) complex [MoO 2 L(OH 2 )]·[MoO 2 L(EtOH)] ( 2 ). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert -butyl hydroperoxide as oxidant. |
| Databáze: | OpenAIRE |
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