Stereoselective Synthesis of Alkenyl Silanes, Sulfones, Phosphine Oxides, and Nitroolefins by Radical C–S Bond Cleavage of Arylalkenyl Sulfides

Autor:	Rong-kang Wang, Wen-Bin Yi, Guo-ping Lu, Ya-mei Lin
Rok vydání:	2017
Předmět:	Silanes 010405 organic chemistry Organic Chemistry 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences chemistry.chemical_compound Stereospecificity chemistry Organic chemistry Stereoselectivity Physical and Theoretical Chemistry Bond cleavage Phosphine
Zdroj:	Organic Letters. 19:1100-1103
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.7b00126
Popis:	A radical-mediated approach has been introduced for the C-S bond activation of arylalkenyl sulfides. The protocol provides an efficient approach for the generation of various alkenes including alkenyl silanes, sulfones, phosphine oxides, and nitroolefins. In most cases, these radical substitutions are performed under metal-free conditions with stereospecificity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5e2d736496f6e532f4cf5a785d365080 https://doi.org/10.1021/acs.orglett.7b00126 Zobrazit plný text záznamu