Liquid chromatographic determination of nine N-methylcarbamates in drinking water
| Autor: | Patrizia Morrica, Paola Fidente, Serenella Seccia |
|---|---|
| Přispěvatelé: | Morrica, Patrizia, Fidente, Paola, Seccia, Serenella |
| Rok vydání: | 2004 |
| Předmět: |
Aldicarb
Clinical Biochemistry post-column derivatization Methomyl Biochemistry Analytical Chemistry chemistry.chemical_compound Water Supply Ethiofencarb Carbaryl Drug Discovery aldicarb and metabolite solid-phase extraction Solid phase extraction Pesticides Molecular Biology Chromatography High Pressure Liquid Pharmacology Chromatography Extraction (chemistry) General Medicine Propoxur chemistry fluorescence detection Polystyrenes Carbamates Carbofuran |
| Zdroj: | Biomedical chromatography : BMC. 19(1) |
| ISSN: | 0269-3879 |
| Popis: | A multi-residue method for the simultaneous extraction from drinking water using solid-phase extraction on LiChrolut EN [poly(styrene-divinylbenzene), PSDVB] and determination of nine N-methylcarbamate pesticides (NMCs) (aldicarb, its metabolites i.e. aldicarb sulfone and aldicarb sulfoxide and carbaryl, carbofuran, dioxacarb, ethiofencarb, methomyl and propoxur) using reversed-phase liquid chromatography was studied. A 1000-fold pre-concentration was achieved and the method was used for determination of the nine pesticides in water, with limits of detection in the range 3–15 ng L−1. For all compounds the recoveries determined at the 0.1 and 1 µg L−1 level generally ranged from 85 to 104% with relative standard deviations (RSD) of 1.4–8.8%. Copyright © 2004 John Wiley & Sons, Ltd. |
| Databáze: | OpenAIRE |
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