Exploitation of the majority rules effect for the accurate measurement of high enantiomeric excess values using CD spectroscopy
| Autor: | Helen M. Seifert, Eric V. Anslyn, Yun-Bao Jiang |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Quantitative Biology::Biomolecules
Circular dichroism Majority rule Acetylene Chemistry Circular Dichroism Metals and Alloys Analytical chemistry Stereoisomerism General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Computational chemistry Materials Chemistry Ceramics and Composites Enantiomeric excess |
| Zdroj: | Chem. Commun.. 50:15330-15332 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c4cc07927b |
| Popis: | A new method for lowering the error of CD based methods for measuring high enantiomeric excess values is described, which exploits the majority rules effect exhibited by certain helical polymers. A proof of principle experiment was conducted. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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