Synthesis, Structural Characterization and Luminescence Studies of the First Akynyl Stabilised Platinum-Cadmiun Complexes
Autor: | J. P. H. Charmant, J. Gómez, A. G. Orpen, L. R. Falvello, J. Forniés, A. Rueda, E. Lalinde, M. T. Moreno |
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Jazyk: | angličtina |
Rok vydání: | 1999 |
Předmět: | |
Zdroj: | RIUR. Repositorio Institucional de la Universidad de La Rioja instname RIUR: Repositorio Institucional de la Universidad de La Rioja Universidad de La Rioja (UR) |
Popis: | The simple 1∶2 adduct (NBu4)2[{Pt(µ-κCα:η2- CCPh)4}(CdCl2)2] 2 containing unusual η2-alkyne Cd interactions, as well as the unexpected tetranuclear dimer (NBu4)2[{Pt(µ-κCαCα-CCPh)4}2(CdCl)2] 1 stabilised by alkynyl bridging ligands and platinum–cadmium bonding interactions, have been characterised by X-ray crystallography and their luminescence properties have been also investigated. |
Databáze: | OpenAIRE |
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