Raman spectroscopic data from Formic Acid Decomposition in subcritical and supercritical water
| Autor: | Elizabeth Rasmussen, Vedant Maheshwari, Per G. Reinhall, John C. Kramlich, Brian R. Pinkard, Igor Novosselov, David J. Gorman |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Formic acid Analytical chemistry Raw material lcsh:Computer applications to medicine. Medical informatics Chemical kinetics 03 medical and health sciences symbols.namesake chemistry.chemical_compound 0302 clinical medicine lcsh:Science (General) Effluent Reaction kinetics 030304 developmental biology Supercritical water 0303 health sciences Multidisciplinary Chemical Engineering Decomposition Supercritical fluid chemistry Carbon dioxide Raman spectroscopy symbols lcsh:R858-859.7 030217 neurology & neurosurgery Gasification lcsh:Q1-390 |
| Zdroj: | Data in Brief, Vol 29, Iss, Pp-(2020) Data in Brief |
| ISSN: | 2352-3409 |
| Popis: | The spectra presented correspond with the research article entitled “Kinetics of Formic Acid Decomposition in Subcritical and Supercritical Water – A Raman Spectroscopic Study” [1]. Data set contains in situ Raman spectra of the quenched effluent stream, which includes varied concentrations of formic acid, water, CO, CO2, and H2 as reaction products. Each spectrum is collected downstream of the subcritical or supercritical water gasification of formic acid, which occurs at a specified temperature, residence time, a constant pressure of 25 MPa, and a constant initial feedstock concentration of 3.6 wt% formic acid. Additionally, calibration spectra of formic acid in water, and spectra of pure carbon dioxide and high concentration formic acid are provided for model development. Finally, a MATLAB code used for baseline subtraction of raw data files is included with the dataset. The full dataset is hosted in Mendeley Data, https://doi.org/10.17632/hjn8xwskng.1. Keywords: Raman spectroscopy, Supercritical water, Formic acid, Gasification, Reaction kinetics |
| Databáze: | OpenAIRE |
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