BODIPY-Thiophene Copolymers asp-Channel Semiconductors for Organic Thin-Film Transistors

Autor:	Hakan Usta, Alyssa-Jennifer Avestro, Antonio Facchetti, Mitchell Denti, Wei Zhao, Damien Boudinet, M. Deniz Yilmaz, J. Fraser Stoddart
Rok vydání:	2013
Předmět:	Materials science Band gap business.industry Mechanical Engineering Analytical chemistry Organic semiconductor chemistry.chemical_compound Semiconductor chemistry Mechanics of Materials Thin-film transistor Thiophene Optoelectronics General Materials Science Charge carrier BODIPY business HOMO/LUMO
Zdroj:	Advanced Materials. 25:4327-4334
ISSN:	0935-9648
Popis:	The synthesis and physicochemical properties of a new class of BODIPY-based donor-acceptor π-conjugated polymers are presented. Solution-processed top-gate/bottom-contact (TG-BC) thin-film transistors on flexible plastic substrates exhibit air-stable p-channel activities with charge carrier mobilities as high as 0.17 cm(2) /V·s and current on/off ratios of 10(5) -10(6) , the highest reported to date for a BODIPY-based semiconductor. The results shown here indicate a significant charge-transport improvement (>10000×) in BODIPY-based polymeric semiconductors, demonstrating its potential in future organic optoelectronic applications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5cbfe844dd5d912c0fdfb64eac30bfeb https://doi.org/10.1002/adma.201300318 Zobrazit plný text záznamu Plný text