Optimal distribution of phosphorus compounds in multi-layered natural fabric reinforced biocomposites
Autor: | E. Verret, Beáta Szolnoki, György Marosi, Attila Farkas, Dániel Vadas, Katalin Bocz, Kata Enikő Decsov |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
Materials science
Polymers and Plastics Distribution (number theory) General Chemical Engineering Phosphorus Organic Chemistry chemistry.chemical_element mechanical properties lcsh:Chemical technology Natural (archaeology) chemistry.chemical_compound chemistry Chemical engineering Polylactic acid Materials Chemistry natural fibre reinforcement lcsh:TA401-492 lcsh:Materials of engineering and construction. Mechanics of materials lcsh:TP1-1185 biopolymers biocomposites Physical and Theoretical Chemistry polylactic acid flame retardancy |
Zdroj: | eXPRESS Polymer Letters, Vol 14, Iss 7, Pp 606-618 (2020) |
Popis: | Flame retardancy and mechanical performance of multi-layered biocomposites, consisting of polylactic acid (PLA) matrix films and plain-woven flax fabrics as reinforcement, were investigated. Full factorial design (32) was applied to evaluate the effects of the distribution of P and N containing compounds between the matrix and the fibrous carrier. Composition property correlations of the composite constituents (i.e. flax fabrics treated in aqueous solutions of diammonium phosphate and urea with differing ratio and concentrations and matrix films with 0 to 20 wt% ammonium polyphosphate based intumescent flame retardant content) were determined by thermogravimetric analyses and open flame tests. Positive interaction between the composite constituents was revealed for green composites consisting of various combinations of treated fabrics and intumescent PLA systems. The biocomposites flame retarded with a combined approach, i.e. with a balanced distribution of P containing additives between the phases, were found to gain improved mechanical performance and fire retardancy. It was confirmed by tensile testing and electron microscopy as well as by UL-94, limiting oxygen index and cone calorimeter tests. As a conclusion, interpretation is given for the optimum found. |
Databáze: | OpenAIRE |
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