Manipulating micro-electric field and coordination-saturated site configuration boosted activity and safety of frustrated single-atom Cu/O Lewis pair for acetylene hydrochlorination

Autor: Chaofeng Huang, Junchen Peng, Dandan Dong, Zongyuan Wang, Hong Yang, Dongyang Qiao, Qinqin Wang, Wei Sun, Minmin Liu, Jiajun Wang, Zhu Mingyuan, Bin Dai, Fei He
Rok vydání: 2023
Předmět:
Zdroj: Nano Research.
ISSN: 1998-0000
1998-0124
DOI: 10.1007/s12274-023-5681-3
Popis: Simultaneously boosting acetylene hydrochlorination activity and avoiding formation of explosive copper acetylide over Cu-based catalyst, which represented a promising alternative to Hg-based and noble metal catalysts, remained challenging. Herein, we fabricated a frustrated single−atom Cu/O Lewis pair catalyst (Cu/O−FLP) by coupling epoxide group (C−O−C) with atom-dispersed Cu−cis−N2C2Cl center to address this challenge. The basic epoxy site modulated the electron-deficient state of Lewis-acidic Cu center and paired with the Cu−cis−N2C2Cl moiety to preferentially break HCl into different electronegative Cu−Clδ− and C−O−Hδ+ intermediates, which further induced both an extra localized electric field to polarize acetylene and a upshift of the d-band center of catalyst, thereby promoting adsorption and enrichment of acetylene by enhancing the dipolar interaction between acetylene and active intermediates. Moreover, the generated Cu−Clδ− and C−O−Hδ+ drastically reduced the energy barrier of rate-limiting step and made vinyl chloride easier to desorb from the Lewis-basic oxygen-atom site rather than traditional Lewis-acidic Cu center. These superiorities ensured a higher activity of Cu/O-FLP compared with its counterparts. Meanwhile, preferential dissociation of HCl endowed single-atom Cu with the coordination-saturated configuration, which impeded formation of explosive copper acetylide by avoiding the direct interaction between Cu and acetylene, ensuring the intrinsic safety during catalysis.
Databáze: OpenAIRE
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