Evidence for termination of intermediate radical species in RAFT-mediated polymerization

Autor:	Matthew P. Tonge, Ronald D. Sanderson, Jean M. McKenzie, L Bert Klumperman, FM Calitz, J. B. McLeary
Přispěvatelé:	Chemical Engineering and Chemistry
Jazyk:	angličtina
Rok vydání:	2003
Předmět:	Reaction mechanism Polymers and Plastics Chemistry Radical Organic Chemistry Radical polymerization Chain transfer Reaction intermediate Inorganic Chemistry Cobalt-mediated radical polymerization Polymerization Polymer chemistry Materials Chemistry Initiation
Zdroj:	Macromolecules, 36(26), 9687-9690. American Chemical Society
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma0353787
Popis:	The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5c5912979f2f3819e5bda7b7d871a09c https://doi.org/10.1021/ma0353787 Zobrazit plný text záznamu