| Popis: |
Covalent organic frameworks (COFs) as crystalline polymers possess ordered nanochannels. When their channels are adorned with catalytically active functional groups, their highly insoluble and fluffy powder texture makes them apt heterogeneous catalysts that can be dispersed in a range of solvents and heated to high temperatures (80-180 °C). This would mean very high catalyst density, facile active-site access, and easy separation leading to high isolated yields. Different approaches have been devised to anchor or disperse the catalytic sites into the nanospaces offered by the COF pores. Such engineered COFs have been investigated as catalysts for many organic transformation reactions. These range from Suzuki-Miyaura coupling, Heck coupling, Knoevenagel condensation, Michael addition, alkene epoxidation, CO |
