Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis
| Autor: | Carolin Hoyer, Lara Hettmanczyk, Biprajit Sarkar, Sinja Manck, Stephan Hohloch |
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| Rok vydání: | 2015 |
| Předmět: |
Metals and Alloys
Mesoionic General Chemistry Photochemistry Electrochemistry Combinatorial chemistry Redox Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Ferrocene Materials Chemistry Ceramics and Composites Redox active Carbene |
| Zdroj: | Chemical Communications. 51:10949-10952 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc01578b |
| Popis: | A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe–Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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