Convenient synthesis of phosphinecarboxamide and phosphinecarbothioamide by hydrophosphination of isocyanates and isothiocyanates

Autor:	Masumi Itazaki, Takanari Matsutani, Toshiyuki Moriuchi, Tomoya Nochida, Hiroshi Nakazawa
Rok vydání:	2020
Předmět:	Primary (chemistry) Chemistry Metals and Alloys General Chemistry Nuclear magnetic resonance spectroscopy Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Solvent Materials Chemistry Ceramics and Composites Hydrophosphination Molecule Organic chemistry Reaction system
Zdroj:	Chemical Communications. 56:443-445
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c9cc08329d
Popis:	Reactions of isocyanates with primary and secondary phosphines without solvent at room temperature afforded the corresponding phosphinecarboxamide (RN(H)COPR'2) in excellent yields. This reaction system is applicable for isothiocyanates. The compounds newly obtained were fully characterized using multielement NMR spectroscopy. In addition, the molecular structure of Cl(CH2)2N(H)COPPh2 was studied by single-crystal X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5bf525f52699690a353c64e6c35a912e https://doi.org/10.1039/c9cc08329d Zobrazit plný text záznamu