| Autor: |
Xianhao Zhang, Qi-Fa Chen, Jintao Deng, Xinyu Xu, Jirui Zhan, Hao-Yi Du, Zhengyou Yu, Meixian Li, Ming-Tian Zhang, Yuanhua Shao |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
Journal of the American Chemical Society. 144(39) |
| ISSN: |
1520-5126 |
| Popis: |
Molecular catalysis of water oxidation has been intensively investigated, but its mechanism is still not yet fully understood. This study aims at capturing and identifying key short-lived intermediates directly during the water oxidation catalyzed by a cobalt-tetraamido macrocyclic ligand complex using a newly developed an in situ electrochemical mass spectrometry (EC-MS) method. Two key ligand-centered-oxidation intermediates, [(L |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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