Open-framework germanates formed by the flexible Ge(10) cluster

Autor:	Mikaela Gustafsson, Kirsten E. Christensen, Lei Shi, Charlotte Bonneau, Xiaodong Zou
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	Crystallography Chemistry Cluster (physics) Mineralogy Crystal structure Mesoporous material Open framework
Popis:	Open-framework germanates have shown promising results in achieving extra-large pores and channels. Pores that extend to the mesoporous range (>20Å) were reported in SU-M. The structure of SU-M is built by the Ge10X28 (Ge10, X = O, OH, F) clusters. This cluster is also found in Ge-pharmacosiderite, Na4Ge9O20, ICMM-7 and SU-61. The Ge10 cluster has a flexibility to form compounds with both high and very low framework densities. © 2008 Elsevier B.V. All rights reserved.
Databáze:	OpenAIRE
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