| Autor: |
Ai-Ling Guo, Dian-Shun Guo, Jian-Ping Ma, Mei Zhao |
| Jazyk: |
angličtina |
| Rok vydání: |
2010 |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| ISSN: |
1600-5368 |
| Popis: |
The crystal structure of the title dimolybdenum complex, [Mo(2)(C(12)H(9)NO)(C(7)H(7)O(2))(2)(CO)(4)], has a quasi-tetra-hedral Mo(2)C(2) cluster core attached to one 3-(8-quinol-yloxy)propanediyl (L) and two methoxy-carbonyl-cyclo-penta-dienyl (Cp') ligands which are coordinated to two Mo atoms: one Mo atom bonds two terminal CO ligands while the other links one terminal and one semi-bridging CO ligand. An intra-molecular C-H⋯N hydrogen bond results in the quinolyl plane of the L ligand approaching and being nearly perpendicular to one of the Cp' rings [88.09 (12)°]. In the supra-molecular structure, a one-dimensional comb-shaped infinite chain is formed approximately along the crystallographic c axis by a combination of inter-molecular C-H⋯O hydrogen bonds and locally generates a C(6) motif. Finally, pairs of inversion-related comb-shaped chains associate into a new ladder-shaped infinite chain through weak π-π stacking inter-actions between neighbouring quinolyl systems (pyridyl centroid-centroid distance = 3.853 Å). |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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