Pd-catalyzed C(sp3 )–C(sp) bond formation in iodocyclobutenes
Autor: | Diego J. Cárdenas, Pedro Almendros, M. Teresa Quirós, Carlos Lázaro-Milla |
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Přispěvatelé: | UAM. Departamento de Química Orgánica |
Jazyk: | angličtina |
Rok vydání: | 2021 |
Předmět: |
Cyclobutene
Allylation Metals and Alloys General Chemistry Química Bond formation Allyl Alcohol Oxidative addition Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Core (optical fiber) chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Surface modification |
Zdroj: | Biblos-e Archivo. Repositorio Institucional de la UAM instname Digital.CSIC. Repositorio Institucional del CSIC |
Popis: | A Pd-catalyzed C(sp3)–C(sp) bond formation for the direct functionalization of cyclobutenes with alkynes has been achieved, suggesting (DFT and control experiments) an unusual pathway of oxidative addition in tertiary iodoalkanes. |
Databáze: | OpenAIRE |
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