A readily accessible ruthenium catalyst for the solvolytic dehydrogenation of amine–borane adducts

Autor:	Zoraida Freixa, Jorge Pérez-Miqueo, Martín Muñoz-Olasagasti, María A. Garralda, Ainara Telleria
Rok vydání:	2014
Předmět:	Inorganic Chemistry chemistry.chemical_compound Aqueous solution Tap water chemistry Organic chemistry Amine gas treating Dehydrogenation Ruthenium catalyst Solvolysis Borane Adduct
Zdroj:	Dalton Transactions. 43:11404
ISSN:	1477-9234 1477-9226
Popis:	The use of the readily available complex [Ru(p-Cym)(bipy)Cl]Cl as an efficient and robust precatalyst for homogeneously catalysed solvolysis of amine-borane adducts to liberate the hydrogen content of the borane almost quantitatively is being presented. The reactions can be carried out in tap water, and in aqueous mixtures with non-deoxygenated solvents. The system is also efficient for the dehydrocoupling of dimethylamine-borane under solvent-free conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5b556e1a17f5d3e26832149ef44a9f36 https://doi.org/10.1039/c4dt01216j Zobrazit plný text záznamu