A readily accessible ruthenium catalyst for the solvolytic dehydrogenation of amine–borane adducts
Autor: | Zoraida Freixa, Jorge Pérez-Miqueo, Martín Muñoz-Olasagasti, María A. Garralda, Ainara Telleria |
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Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Dalton Transactions. 43:11404 |
ISSN: | 1477-9234 1477-9226 |
Popis: | The use of the readily available complex [Ru(p-Cym)(bipy)Cl]Cl as an efficient and robust precatalyst for homogeneously catalysed solvolysis of amine-borane adducts to liberate the hydrogen content of the borane almost quantitatively is being presented. The reactions can be carried out in tap water, and in aqueous mixtures with non-deoxygenated solvents. The system is also efficient for the dehydrocoupling of dimethylamine-borane under solvent-free conditions. |
Databáze: | OpenAIRE |
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