Silylcupration and Copper-Catalyzed Carbomagnesiation of Ynamides: Application to Aza-Claisen Rearrangement

Autor:	Hiroto Yasui, Hideki Yorimitsu, Koichiro Oshima
Rok vydání:	2008
Předmět:	Claisen rearrangement Chemistry Reagent Copper catalyzed Organic chemistry Stereoselectivity General Chemistry Protonolysis
Zdroj:	Bulletin of the Chemical Society of Japan. 81:373-379
ISSN:	1348-0634 0009-2673
Popis:	Treatment of ynamides with silylcopper reagents resulted in silylcupration to afford (E)-β-silylenamides, after protonolysis, in good yields with high regio- and stereoselectivity. Reaction of ynam...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5b3d468d63cfb1cd21d4777ce12009a6 https://doi.org/10.1246/bcsj.81.373 Zobrazit plný text záznamu