Kinetics of Radical Polymerization. Li. Investigation of the Radical Bulk Polymerization of Vinyl Acetate by the Rotating Sector Method at Different Temperatures
| Autor: | Ferenc Tüdös, T. Földes-Berezsnich, Tibor Pernecker |
|---|---|
| Rok vydání: | 1990 |
| Předmět: |
Kinetic chain length
Nitroxide mediated radical polymerization Polymers and Plastics Chemistry Radical polymerization General Engineering Chain transfer General Chemistry Photochemistry Cobalt-mediated radical polymerization Polymerization Catalytic chain transfer Materials Chemistry Ceramics and Composites Living polymerization Physical chemistry |
| Zdroj: | Journal of Macromolecular Science: Part A - Chemistry. 27:1029-1039 |
| ISSN: | 0022-233X |
| DOI: | 10.1080/00222339009349673 |
| Popis: | The absolute values of the chain propagation and termination rate coefficients of VAc radical polymerization were determined at 30, 35, 40, and 50°C. Based on these results, the following Arrhenius equations were obtained: and The calculated activation energies of the elementary reaction steps are compared to the literature data, and the differences are discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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