Exopolysaccharides (EPS) as anti-corrosive additives for coatings
| Autor: | Wessel Holtman, Gabriele Ferrari, Rik Breur, Ted Slaghek, Marco Vennik, Jurgen Scheerder |
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| Rok vydání: | 2012 |
| Předmět: |
Industrial Innovation Healthy Living
TS - Technical Sciences EELS - Earth Environmental and Life Sciences Exopolysaccharides General Chemical Engineering chemistry.chemical_element Zinc engineering.material Electrochemistry Corrosion Metal Coating Coatings Materials Chemistry Food and Nutrition Organic chemistry MPC - Materials Performance CentreFI - Functional Ingredients chemistry.chemical_classification Chemistry Organic Chemistry Anti-corrosion Polymer Surfaces Coatings and Films Waterborne polymers Sustainability Chemical engineering visual_art engineering visual_art.visual_art_medium Mechatronics Mechanics & Materials Life Dispersion (chemistry) |
| Zdroj: | Progress in Organic Coatings, 75(3), 224-230 Progress in Organic Coatings 75 (2012) 3 Progress in Organic Coatings, 75, 224-230 |
| ISSN: | 0300-9440 |
| DOI: | 10.1016/j.porgcoat.2012.05.003 |
| Popis: | Exopolysaccharides (EPS) are a class of renewable polymers that show interesting anti-corrosive properties and could potentially be used as an alternative for zinc phosphates. When combined with a waterborne styrene-acrylic polymer dispersion (SA-1), exopolysaccharides were shown to give an improvement in the anti-corrosive performance. Electrochemical studies show higher charge transfer resistance (R ct) values for the SA-1/EPS combinations as compared to the SA-1 itself suggesting that in the presence of EPS less corrosion took place. Outdoor exposure test shows that the presence of EPS188 gave good corrosion protection for up to a year when exposed under marine conditions. The distribution of EPS modification throughout the coating was made visible using Confocal Laser Scanning Microscopy and indicated that EPS was distributed rather homogeneously. A working mechanism was proposed in which the carboxylic acid groups on the oxidised EPS form a complex with iron ions formed by the anodic reaction and this insoluble complex forms a protective layer between the coating and metal. The results in this paper show that by using renewable polysaccharide additives the anti-corrosive coating performance can be improved. |
| Databáze: | OpenAIRE |
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