Deracemization in a complex quaternary system with a second‐order asymmetric transformation using phase diagram studies
Autor: | Francesco Marin, Paul Tinnemans, Marine Hoquante, Hugo Meekes, Anne Laurent, Elias Vlieg, Gérard Coquerel, Ryusei Oketani, Pascal Cardinael, Yves Geerts, Clément Brandel |
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Přispěvatelé: | Sciences et Méthodes Séparatives (SMS), Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Normandie Université (NU), Propre |
Rok vydání: | 2019 |
Předmět: |
Chemistry
Group (mathematics) 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Organic Chemistry General Chemistry Solid State Chemistry [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences [SPI.MAT]Engineering Sciences [physics]/Materials Theoretical physics Transformation (function) Tetrahedron [CHIM.CRIS]Chemical Sciences/Cristallography Order (group theory) Cover (algebra) Symmetry breaking Quaternary ComputingMilieux_MISCELLANEOUS Phase diagram |
Zdroj: | Chemistry – A European Journal Chemistry-A European Journal Chemistry-A European Journal, Wiley-VCH Verlag, 2019, 25 (61), pp.13890-13898. ⟨10.1002/chem.201903338⟩ Chemistry : a European Journal, 25, 61, pp. 13890-13898 Chemistry : a European Journal, 25, 61, pp. 13837-13837 Chemistry : a European Journal, 25, 13890-13898 Chemistry : a European Journal, 25, 13837-13837 |
ISSN: | 0947-6539 1521-3765 |
DOI: | 10.1002/chem.201903338 |
Popis: | A productive deracemization process based on a quaternary phase diagram study of a naphthamide derivative is reported. New racemic compounds of an atropisomeric naphthamide derivative have been discovered, and a quaternary phase diagram has been constructed that indicated that four solids are stable in a methanol/H |
Databáze: | OpenAIRE |
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