Free-Standing Porous Carbon Nanofiber/Carbon Nanotube Film as Sulfur Immobilizer with High Areal Capacity for Lithium–Sulfur Battery
| Autor: | Ze Zhang, Sheng Liu, Xue-Ping Gao, Ye-Zheng Zhang, Guo-Ran Li |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
chemistry.chemical_element Lithium–sulfur battery 02 engineering and technology Carbon nanotube 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Sulfur Electrospinning Cathode 0104 chemical sciences law.invention Carbon film Chemical engineering chemistry law Nanofiber General Materials Science 0210 nano-technology Sulfur utilization |
| Zdroj: | ACS Applied Materials & Interfaces. 10:8749-8757 |
| ISSN: | 1944-8252 1944-8244 |
| Popis: | Low sulfur utilization and poor cycle life of the sulfur cathode with high sulfur loadings remain a great challenge for lithium–sulfur (Li–S) battery. Herein, the free-standing carbon film consisting of porous carbon nanofibers (PCNFs) and carbon nanotubes (CNTs) is successfully fabricated by the electrospinning technology. The PCNF/CNT film with three-dimensional and interconnected structure is promising for the uniformity of the high-loading sulfur, good penetration of the electrolyte, and reliable accommodation of volumetric expansion of the sulfur cathode. In addition, the abundant N/O-doped elements in PCNF/CNT film are helpful to chemically trap soluble polysulfides in the charge–discharge processes. Consequently, the obtained monolayer S/PCNF/CNT film as the cathode shows high specific capacity, excellent cycle stability, and rate stability with the sulfur loading of 3.9 mg cm–2. Moreover, the high areal capacity of 13.5 mA h cm–2 is obtained for the cathode by stacking three S/PCNF/CNT layers with... |
| Databáze: | OpenAIRE |
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