Stereocontrolled synthesis of unnatural cyclic dipeptides containing an l-valine unit

Autor: Daniele Balducci, Gianni Porzi, Alessandro Grandi, Sergio Sandri
Přispěvatelé: D. Balducci, A. Grandi, G. Porzi, S. Sandri
Rok vydání: 2005
Předmět:
Zdroj: Tetrahedron: Asymmetry. 16:1453-1462
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2005.03.006
Popis: Stereoselective synthesis of unusual nonproteinogenic dipeptides 7a , b , d , e and h and 13b and i , containing an l -valine unit and a cyclic unnatural α-amino acid, has been accomplished starting from the l -valine derived chiral synthon 1 . The absolute configurations of the new stereocentres were assigned on the basis of 1 H NMR spectra.
Databáze: OpenAIRE