Stereocontrolled synthesis of unnatural cyclic dipeptides containing an l-valine unit
Autor: | Daniele Balducci, Gianni Porzi, Alessandro Grandi, Sergio Sandri |
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Přispěvatelé: | D. Balducci, A. Grandi, G. Porzi, S. Sandri |
Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Tetrahedron: Asymmetry. 16:1453-1462 |
ISSN: | 0957-4166 |
DOI: | 10.1016/j.tetasy.2005.03.006 |
Popis: | Stereoselective synthesis of unusual nonproteinogenic dipeptides 7a , b , d , e and h and 13b and i , containing an l -valine unit and a cyclic unnatural α-amino acid, has been accomplished starting from the l -valine derived chiral synthon 1 . The absolute configurations of the new stereocentres were assigned on the basis of 1 H NMR spectra. |
Databáze: | OpenAIRE |
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