Spatial modulation spectroscopy of graphene sheets

Autor: Gregory V. Hartland, Shun S. Lo, Vaishnav Murthy, Zhongming Li, Nicolas Havard
Rok vydání: 2014
Předmět:
Zdroj: The Journal of Chemical Physics. 140:074203
ISSN: 1089-7690
0021-9606
DOI: 10.1063/1.4865833
Popis: Two different samples of graphene, multi-layer flakes on Si/SiO2 substrates and single layer graphene on glass, have been examined by reflectivity contrast and spatial modulation spectroscopy measurements. For the multi-layer graphene flakes, the reflectivity contrast and spatial modulation spectroscopy measurements are in good agreement, validating the application of spatial modulation spectroscopy to two-dimensional samples. The measurements for single layer graphene on glass show features that correspond to increases and decreases in reflectivity. The features with increased reflectivity are assigned to small regions of multilayer graphene or polymer, and the features with decreased reflectivity are assigned to holes in the graphene film. Using a model for thin film reflectivity we calculate the size dependent spatial modulation signal for the holes, and find that a significant number of holes have a larger than expected signal. This could arise from the presence of multi-layers of graphene in the sample, or because of optical resonance effects for the holes.
Databáze: OpenAIRE