Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds
| Autor: | Yazhen Xue, Jingfeng Huo, Jianbo Wang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Bis(pinacolato)diboron
010405 organic chemistry Metals and Alloys Regioselectivity Substrate (chemistry) General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Electrophilic amination Electrophile Materials Chemistry Ceramics and Composites Copper catalyzed Diazo |
| Zdroj: | Chemical Communications. 54:12266-12269 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | A Cu(i)-catalyzed aminoborylation reaction of styrenes is reported. In this transformation, diazo compounds are used as the electrophilic amination agent. The in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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