Insertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to OH bond
| Autor: | Akira Sekiya, Yasuhisa Matsukawa, Masanori Tamura, Heng-dao Quan, Junji Mizukado |
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| Rok vydání: | 2005 |
| Předmět: |
Difluorocarbene
Hydrogen bond Organic Chemistry Oxide Alcohol General Medicine Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Nucleophile Insertion reaction Polymer chemistry Environmental Chemistry Organic chemistry Phenol Physical and Theoretical Chemistry Selectivity Pyrolysis |
| Zdroj: | Journal of Fluorine Chemistry. 126:365-369 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2005.01.012 |
| Popis: | ROCHF 2 -type fluorinated ethers were synthesized by the reaction of hexafluoropropene oxide (HFPO) with alcohol or phenol. In this reaction, although the insertion reaction of difluorocarbene to O H bond and the nucleophilic attack of alcohol or phenol to HFPO were competition, the insertion reaction proceeded predominantly to give fluorinated ether in the case of low nucleophilic alcohol or phenol. In addition, high reaction pressure is advantageous to the selectivity of the fluorinated ethers in the reaction of HFPO with (CF 3 ) 2 CHOH or C 6 F 5 OH. |
| Databáze: | OpenAIRE |
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