Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry
| Autor: | Dilek Ünlüer, Zekeriya Biyiklioğlu, Yasemin Ünver, Turgut Keleş |
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| Přispěvatelé: | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü, Keleş, Turgut |
| Rok vydání: | 2021 |
| Předmět: |
diethylamino
Working electrode Chemistry Multidisciplinary Electrochemistry Medicinal chemistry Redox Article Phthalonitrile Metal Synthesis chemistry.chemical_compound Synthesis diethylamino phthalocyanine electrochemistry biology Cationic polymerization Phthalocyanine General Chemistry biology.organism_classification Diethylamino phthalocyanine electrochemistry chemistry visual_art visual_art.visual_art_medium Tetra Kimya Ortak Disiplinler |
| Zdroj: | Turkish Journal of Chemistry Volume: 45, Issue: 1 17-25 |
| ISSN: | 1303-6130 1300-0527 |
| DOI: | 10.3906/kim-2007-47 |
| Popis: | 3-[5-(diethylamino)-2-formylphenoxy]phthalonitrile ( n-TY-CN ), metallophthalocyanines n-TY-Co , n-TY-Cu , and n-TY-Mn bearing [5-(diethylamino)-2-formylphenoxy] groups at nonperipheral positions were prepared for the first time. These compounds were characterized with IR, NMR (only for n-TY-CN ), mass and UV-vis (except n-TY-CN ) spectroscopy. Voltammetric characterizations of n-TY-Co , n-TY-Cu , and n-TY-Mn revealed that while n-TY-Co , n-TY-Cu , and n-TY-Mn showed characteristic Pc ring and/or metal-based reduction reaction, n-TY-Co , n-TY-Cu , and n-TY-Mn were coated on the working electrode during the oxidation processes owing to the cationic electropolymerizations of the [5-(diethylamino)-2-formylphenoxy] substituents. |
| Databáze: | OpenAIRE |
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