Polyguanamine Derivative-Based Supramolecular Assemblies with Multiple Hydrogen Bonding and Their Metal-Scavenging Abilities
| Autor: | Keito Fukushi, Yuji Shibasaki, Atsuhiro Fujimori, Haruka Maruyama |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Hydrogen bond
technology industry and agriculture Supramolecular chemistry macromolecular substances Surfaces and Interfaces Condensed Matter Physics Metal chemistry.chemical_compound chemistry Derivative (finance) visual_art Polymer chemistry Electrochemistry visual_art.visual_art_medium General Materials Science Scavenging Spectroscopy Triazine |
| Zdroj: | Langmuir. 36:3770-3781 |
| ISSN: | 1520-5827 0743-7463 |
| DOI: | 10.1021/acs.langmuir.0c00283 |
| Popis: | Polyguanamine derivatives having cyclic moieties constituted by two phenyl and two triazine rings have been synthesized, and a supramolecular organization based on their multiple hydrogen-bonding ability was investigated. The obtained polyguanamine derivatives with cyclic moieties were transparent and amorphous in the bulk state and showed excellent mechanical strength emanating from multiple hydrogen bonds, owing to the abundant amino groups present in the structure. These polyguanamine derivatives formed stable monolayers at the air/water interface. The multilayers were transferred using the Langmuir-Blodgett method, and they formed highly periodic layered structures. To evaluate the metal scavenging ability of the cyclic moieties, the metal ions, Cd |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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