Polyaniline modified magnetic nanoparticles coated with dicationic ionic liquid for effective removal of rhodamine B (RB) from aqueous solution
| Autor: | Muggundha Raoov, Mohamad Shariff Shahriman, Saliza Asman, Sharifah Mohamad, Ninie Suhana Abdul Manan, Nur Nadhirah Mohamad Zain, Suhaila Mohd Yaman |
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| Rok vydání: | 2018 |
| Předmět: |
Thermogravimetric analysis
Materials science Aqueous solution Exothermic process General Chemical Engineering 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Adsorption chemistry Ionic liquid Polyaniline Rhodamine B Fourier transform infrared spectroscopy 0210 nano-technology Nuclear chemistry |
| Zdroj: | RSC advances. 8(58) |
| ISSN: | 2046-2069 |
| Popis: | Polyaniline (PANI) modified magnetic nanoparticle (MNP) nanocomposites coated with newly synthesized dicationic ionic liquid (DICAT) forming MNP-PANI-DICAT were successfully synthesized as a potential material for the removal of Rhodamine B (RB) from water samples. The synthesized material was successfully characterized using a few techniques such as Fourier transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), thermo gravimetric analysis (TGA), Brunauer–Emmett–Teller (BET), and transmission electron microscopy (TEM) analysis. Several parameters have been optimized to enhance the efficiency of the removal process. The adsorption kinetics were investigated and the results showed that MNP-PANI-DICAT was best fitted to a pseudo-second order model for the adsorption of RB. As for the isotherm studies, Temkin's model was found to fit well with the adsorption isotherm of RB on MNP-PANI-DICAT. Other than that, thermodynamics results showed negative values of ΔG° for the adsorption of RB, which indicated that the process is thermodynamically feasible, spontaneous and chemically controlled at lower temperature. The negative value of enthalpy ΔH° (−40.41) indicated that the adsorption was an exothermic process. The percentage removal of RB was found to be 94.7% by MNP-PANI-DICAT under optimized conditions. |
| Databáze: | OpenAIRE |
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