Production of low molecular weight esters using vegetable oils or butter oil as reaction media

Autor: Shirley C. Chang, Ross E. Williams, Chantel J. Dicaire, Frank W. Welsh
Jazyk: angličtina
Rok vydání: 1991
Předmět:
Popis: Corn oil, peanut oil, sunflower oil, soybean oil, canola oil, olive oil and butter oil were tested as replacements for nonaqueous solvents in the lipase mediated biosynthesis of ethyl butyrate, butyl butyrate, isoamyl butyrate and isoamyl acetate. The most effective oils tested were butter oil, soybean oil, peanut oil and olive oil (yield = 50–60% after 16 h incubation at 25°C) while corn oil was least effective (yield = 38%). Higher yields were obtained, for all ester syntheses, at a reaction temperature of 50°C. Drying agents were shown to have no effect or to inhibit the synthesis. Of the four enzymes tested, Candida cylindracea lipase was the most effective enzyme for ethyl butyrate synthesis.
Databáze: OpenAIRE