Facile, catalyst-free cascade synthesis of sulfonyl guanidinesviacarbodiimide coupling with amines
| Autor: | Arun Jyoti Borah, Prodeep Phukan, Debojit Hazarika |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Sulfonyl
chemistry.chemical_classification 010405 organic chemistry Metals and Alloys Substrate (chemistry) General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Coupling (electronics) chemistry.chemical_compound chemistry Cascade Yield (chemistry) Materials Chemistry Ceramics and Composites Carbodiimide |
| Zdroj: | Chemical Communications. 55:1418-1421 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc08564a |
| Popis: | An expeditious catalyst-free cascade coupling of N,N-dibromoarylsulfonamides with isonitriles and amines via carbodiimide intermediates has been developed. The protocol represents an elegant pathway for sulfonyl guanidines at room temperature within a short time with high yields and wide substrate scope. The carbodiimide intermediate could also be isolated in an appreciable yield. |
| Databáze: | OpenAIRE |
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